Evaluation of the photocatalytic activity of the FN1® coating on ignimbrite (sillar) in Arequipa - Peru

Authors

  • L.L. Ramos Villa Universidad Nacional de San Agustín de Arequipa. Facultad de Ingeniería de Procesos. Arequipa, Perú
  • J.C. Santiago Contreras Universidad Nacional Mayor De San Marcos. Facultad de Química e Ingeniería Química. Lima, Perú
  • R.B. Guzman Ale Universidad Nacional de San Agustín de Arequipa. Facultad de Ingeniería de Procesos. Arequipa, Perú

DOI:

https://doi.org/10.5377/nrc.v37i01.18322

Keywords:

Photocatalytic Materials, TiO2, Ignimbrite

Abstract

The photocatalytic activity of a suspension of commercial titanium dioxide (FN1), deposited on a porous ignimbrite stone, widely used as a construction material in Arequipa-Peru, was evaluated in order to generate surfaces with self-cleaning properties in urban buildings. The suspension was applied on one side of the ignimbrite substrate by two methods: spray-coating and brush-coating. To evaluate that its application does not alter the physical aspect of the ignimbrite substrate surface, the color coordinates were determined by the CieL*a*b* method, after the application of FN1 giving a maximum total variation of 2.49, showing a good visual compatibility of the coating with the ignimbrite surface. The photocatalytic activity was evaluated by using photobleaching tests with the dyes 2,6-dichloroindophenol (DCIP) and methylene blue (AM), under simulated sunlight irradiation. The highest photocatalytic efficiency was obtained with the ignimbrite substrate coated with 3 layers by spraying FN1, which showed a photodegradation of AM and DCIP of 75.07% and 100% at 120 min and 5 min of irradiation, respectively.

Downloads

Download data is not yet available.
Abstract
252
PDF (Español (España)) 75

References

Bai, X., Yang, S., Tan, C., Jia, T., Guo, L., Song, W., Jian, M., Zhang, X., Zhang, Z., Wu, L., Yang, H., Li, H., Hao, D., (2022). Synthesis of TiO2 based superhydrophobic coatings for efficient anti-corrosion and self-cleaning on stone building surface. Journal of Cleaner Production, 380(1), 134975.

Bergamonti, L., Predieri, G., Paz, Y., Fornasini, L., Lottici, P.P., Bondioli, F. (2017). Enhanced self-cleaning properties of N-doped TiO2 coating for Cultural Heritage. Microchemical Journal, 133, 1-12.

Binas, V., Papadaki, D., Maggos, Th., Katsanaki, A., Kiriakidis, G. (2018). Study of innovative photocatalytic cement based coatings: The effect of supporting materials. Construction and Building Materials, 168, 923–930.

Calia, A., Lettieri, M., Masieri, M. (2016). Durability assessment of nanostructured TiO2 coatings applied on limestones to enhance building surface with self-cleaning ability. Building and Environment, 110, 1-10.

Chen, J., Poon, C. (2009). Photocatalytic construction and building materials: From fundamentals to applications. Building and Environment, 44(9), 1899–1906.

Crupi, V., Fazio, B., Gessini, A., Kis, Z., La Russa, M. F., Majolino, D., Masciovecchio, C., Ricca, M., Rossi, B., Ruffolo, S. A., Venuti, V. (2018). TiO2–SiO2–PDMS nanocomposite coating with self-cleaning effect for stone material: Finding the optimal amount of TiO2. Construction and Building Materials, 166, 464–471.

Drdácký, M., Lesák, J., Rescic, S., Slížková, Z., Tiano, P., Valach, J. (2012). Standardization of peeling tests for assessing the cohesion and consolidation characteristics of historic stone surfaces. Materials and Structures, 45, 505–520.

García, O., Malaga, K. (2012). Definition of the procedure to determine the suitability and durability of an anti-graffiti product for application on cultural heritage porous materials. Journal of Cultural Heritage, 13(1), 77-82.

Gonzales, V., De La Vera Cruz, P., Guzman, R., Lavalle, H. S., Mayhua, F. M., Chambi, V. N. (2018). Estudio de daños y contaminación atmosférica en los monumentos históricos de la ciudad de Arequipa, Perú. Revista Noctua – Arqueologia e Patrimônio,

Kanth, A.P., Soni, A.K. (2023). Application of nanocomposites for conservation of materials of cultural heritage. Journal of Cultural Heritage, 59, 120–130.

Khannyra, S., Mosquera, M.J., Addou, M., Gil, M.L.A. (2021). Cu-TiO2/SiO2 photocatalysts for concrete-based building materials: Self-cleaning and air de-pollution performance. Construction and Building Materials, 313, 125419.

La Russa, M. F., Ruffolo, S. A., Rovella, N., Belfiore, C. M., Palermo, A. M., Guzzi, M. T., Crisci, G. M. (2012). Multifunctional TiO2 coatings for Cultural Heritage. Progress in Organic Coatings, 74(1), 186-191.

La Russa, M. F., Rovella, N., Alvarez, M., C. Belfiore, M., Pezzinoc, A., Crisci, G. M., Ruffoloa, S. A. (2016). Nano-TiO2 coatings for cultural heritage protection: The role of the binder on hydrophobic and self-cleaning efficacy. Progress in Organic Coatings, 91, 1–8

Luna, M., Delgado, J.J., Romero, I., Montini, T., Almoraima, M.L., Martínez, J., Fornasiero, P., Mosquera, M.J. (2022). Photocatalytic TiO2 nanosheets-SiO2 coatings on concrete and limestone: An enhancement of de-polluting and self-cleaning properties by nanoparticle design. Construction and Building Materials, 338, 127349.

Mills, A., McGrady, M., Wang, J., Hepburn, J. (2008). A Rapid Method of Assessing the Photocatalytic Activity of Thin TiO2 Films Using an Ink Based on the Redox Dye 2,6- Dichloroindophenol. International Journal of Photoenergy, 2008, 6.

Pinho, L., Mosquera, MJ. (2011). Titania–Silica nanocomposite photocatalysts with application in stone self-cleaning. J Phys Chem C, 115(46), 22851–62.

Quagliarini, E., Bondioli, F., Goffredo, G. B., Licciulli, A., Munafò, P. (2012a). Smart surfaces for architectural heritage: Preliminary results about the application of TiO2-based coatings on travertine. Journal of Cultural Heritage, 13(2), 204-209.

Quagliarini, E., Bondioli, F., Goffredo, G. B., Cordoni, C., Munafò, P. (2012b). Self-cleaning and de-polluting stone surfaces: TiO2 nanoparticles for limestone. Construction and Building Materials, 37, 51–57.

Sanjurjo, J., Vidal, J. R., Simões, C. A., Fernández, D. (8-10 de octubre 2007). Deterioration of granite ashlars employed in a historic building in the city of a coruna (spain). VII Congreso Iberico de Arqueometría, Madrid, España.

Published

2024-07-10

How to Cite

Ramos Villa, L., Santiago Contreras, J., & Guzman Ale, R. (2024). Evaluation of the photocatalytic activity of the FN1® coating on ignimbrite (sillar) in Arequipa - Peru. Nexo Scientific Journal, 37(01), 34–44. https://doi.org/10.5377/nrc.v37i01.18322

Issue

Section

Articles