Study of the kinetics of Cu and Hg adsorption from binary solutions using chitosan
DOI:
https://doi.org/10.5377/nexo.v24i1.591Keywords:
Adsorption kinetics, Binary solution, Chitosan, Kinetic models, Shrimp shellAbstract
In this work, the adsorption kinetic of Cu(II) and Hg(II) onto chitosan was studied from a binary solution at different initial concentration of metallic ions, at different particle sizes and agitation rate. Chitosan was obtained from shrimp shells. Solutions of 1 L of Cu(II) and Hg(II) were placed in contact with 2 g of chitosan and the mixture was agitated by 8 h. Afterwards, the samples were analysed by atomic absorption. The experimental data were tested by application of kinetic models of pseudo-first order and pseudo-second order. The results of adsorption process showed that in the most cases, both ions were effectively adsorbed by chitosan. The percentage of adsorption was 43-100 % and 94-100 % for Cu(II) and Hg(II), respectively. The results also showed that at low concentrations, experimental data were better adjusted by pseudo-first order models; meanwhile, at high concentration, the data were well described by the pseudo-second model. Therefore, the rate-limiting step is the adsorption reaction and not mass transfer.
Keywords: Adsorption kinetics; Binary solution; Chitosan; Kinetic models; Shrimp shell
DOI: http://dx.doi.org/10.5377/nexo.v24i1.591
Nexo, Vol. 24, No. 1, pp. 20-32, 2011
Downloads
1552
Downloads
How to Cite
Issue
Section
License
The authors who publish in Nexo Scientific Journal agree to the following terms:
- Authors retain the copyright and grant the journal the right of the first publication under the license Creative Commons Attribution License, which allows others to share the work with a recognition of the authorship of the work and the initial publication in Nexo Scientific Journal.
- Authors may separately establish additional agreements for the non-exclusive distribution of the version of the work published in the journal (for example, in an institutional repository or a book), with the recognition of the initial publication in Nexo Scientific Journal.
- Authors are allowed and encouraged to disseminate their works electronically (for example, in institutional repositories or in their own website) before and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published works.